[Poly(Thiourea-Formaldehyde) - Epoxy resin)] Nanomagnetic Full -IPN's for Removal of Heavy Metals from Aqueous Solution : Synthesis and Characterization

  • Salah Sh.Al,luaibi Department of Chemistry, College of Science, University of Basr a, Iraq2
  • Samia Mezhr Merdas 1Department of Chemistry, College of Science, University of Thi-Qar, Iraq
  • Sajid Hassan Guzar 3Department of Chemistry, College of Education for pure sciences , University of Kerbala, Iraq
Keywords: Magnetic nanoparticles, Polymer nanocomposites, Heavy Metals, Adsorption Studies

Abstract

In this work, a batch adsorption study was conducted to investigate the removal efficiency of lead (II), Copper (II) and Cadmium (II) from aqueous solutions by (poly (thiourea-Formaldehyde-Epoxy resin) nanomagnetic Full-IPN's (NM Full-IPN's). The NM Full-IPN's was synthesized by sequential polymerization with presence Fe3O4 nanoparticles. The chemical structure and surface morphology of NM Full-IPNS resin nanoparticles were characterized by Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The chemical structure and surface morphology of NM Full-IPNS resin nanoparticles were characterized by Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The thermal properties of (NM Full- IPN's) has been evaluated by Thermogravimetric analysis (TGA) and Differential Scanning Calorimetric (DSC). Adsorption of Pb (II), Cu(lI) and Cd(II) onto NM Full- IPN's agreed well with the Langmuir model, as revealed by the higher values of correlation coefficients. The results indicate that NM Full- IPN's could be used as efficient adsorbent for the removal of Pb (II), Cu(lI) and Cd(II) from aqueous solution

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Freundlich Isotherm Parameters

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/n KF R2F Qm (mg g-1) b (L g–1) R2L Pb2+ 7.987 6.098 0.853 2.564 1.423 0.898 Cd 2+ 1.117 0.629 0.999 6.944 0.0438 0.999 Cu2+ 1.058 0.539 0.892 1.628 0.126 0.981

J Journal of Education for Pure Science- University of Thi-Qar Vol.11, No.2 (Nove, 2021)

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Published
2022-04-07